In a pot, add water, kosher salt, brown sugar, black pepper, minced garlic, dried thyme, and cayenne pepper. Bring the mixture to a boil, stirring until salt and sugar dissolve completely.
Remove from heat and let the brine cool completely. Never add pork to hot brine.
Place the thick pork chop in a 1-gallon Ziplock bag. Pour the cooled brine over the chop. Make sure it is fully covered. Remove excess air and seal the bag.
Refrigerate for 24 hours.
After 24 hours, remove the pork chop from the brine. Rinse under cold water to remove excess salt. Pat dry using paper towels.
Rub olive oil all over the pork chop. Generously apply your favorite pork seasoning on all sides.
Fill your smoker with pecan pellets. Preheat to 180°F.
Place the pork chop rib-side down on the smoker. Smoke for 3 to 4 hours or until the internal temperature reaches 140°F. Use a meat thermometer and check in the center of the loin.
Remove the pork chop from the smoker and place it on a cutting board. Coat the entire chop with butter. Sprinkle granulated sugar evenly on all sides.
Using a propane or butane torch, carefully caramelize the sugar until golden brown. This creates a crispy, sweet crust.
Let rest for 10 minutes before slicing.
Serve and enjoy your homemade Perry’s Pork Chop!